Indexing Metadata
Microwave Synthesis, Reactivity, Spectral and Thermal Analysis of Some Binary/Mixed Ligand Oxovanadium(IV) Complexes |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Microwave Synthesis, Reactivity, Spectral and Thermal Analysis of Some Binary/Mixed Ligand Oxovanadium(IV) Complexes |
| 2 | Creator | Author's name, affiliation, country | A. P. MISHRA, L.R. PANDEY and RAJENDRA K JAIN*
Synthetic Inorganic & Coordination Chemistry Laboratories, Department of Chemistry,
Dr. H.S. Gour Central University, Sagar (M.P.)-470 003, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Microwave synthesis, Oxovanadium(IV), Binary/mixed ligand, Thermal analyses |
| 4 | Description | Abstract | Microwave-assisted synthesis is a branch of green chemistry. The salient features of microwave approach are shorter reaction times, simple reaction conditions and enhancements in yields. Vanadium containing compounds have their utility in various physicochemicals, biochemical physiological, enzymatic and catalytic processes. Novel six binary/mixed ligand oxovanadium(IV) complexes [VO(deb)(H2O)](I), [VO(deb)(hq)(H2O)](II), [VO(dpeda) 2].SO4.H2O(III), [VO(dndsa)(H2O) 2].SO4.3H2O(IV), [VO(tcne)].(VO3) 2.H2O(V), [VO(dnph) 2(VO3)2].H2O(VI) have been synthesized by conventional as well as microwave methods. These compounds have been characterized by elemental analyses, thermal data, FAB mass, FT-IR, molar conductance, electronic spectra, ESR and magnetic measurements. FAB mass and Thermal data show degradation pattern of the complexes. The thermal behavior of complexes shows that the hydrated complexes lose water molecules of hydration in the first step; followed by decomposition of ligand molecules in the subsequent steps. The reactivity and substitution behaviour of the synthesized complexes have also been studied. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 1 , Number (1), (2012) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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