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2,4,4,6-Tetrabromocyclohex-2,5-dien-1-one:
An Excellent Reagent for Dibromination of Methyl at C-6 in Biginelli Compounds |
DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
1 | Title | Title of Document | 2,4,4,6-Tetrabromocyclohex-2,5-dien-1-one:
An Excellent Reagent for Dibromination of Methyl at C-6 in Biginelli Compounds |
2 | Creator | Author's name, affiliation, country | SUDHIR C PAL*, GOPAL C PATRA, SANKAR C BHUNIA and MONOJ K ROY Chemistry Department, Midnapore College, Midnapore, W.B., India |
3 | Subject | Dicipline(s) | Chemical Science |
3 | Subject | Keywords | 2,4,4,6-Tetrabromocyclohex-2-en-1-one, Biginelli compounds, Dibromination, Bromine |
4 | Description | Abstract | Biginelli compounds (ethyl 4-substituted-2-oxo-1,2,3,4-tetrahydropyrimidine-6-carboxylates) prepared from cyclodehydration of ethyl acetoacetate, urea and aromatic (or aliphatic) aldehydes have been subjected to bromination using (i) Br2/CHCl3 (ii) Br2/AcOH and (iii) 2,4,4,6-tetrabromocyclohex-2-en-1-one (TBCO) separately. The last one viz., TBCO is found to be the best reagent in preparing the 6-dibromethyl derivative in terms of yield and green context. |
5 | Publishers | Organizing agency, location | WWW Publications, India |
6 | Contributor | Sponsor(s) | - |
7 | Date | Date (YYYY-MM-DD) | - |
8 | Type | Status & genre | Peer-reviewed Article |
8 | Type | Type | |
9 | Formate | File Formate | PDF |
10 | Identifier | Uniform Resource Identifier | Click Here |
10 | Identifier | Digital Object Identifier | |
11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 1 , Number (2), (2012) |
12 | Lanuguage | English=en | en |
13 | Relation | Supp.files | |
14 | Coverage | | - |
15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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